Amitabh Bachchan — Jaya Bhaduri
This is one of those rare cases were a real life couple had great chemistry in the reel world. Although Jaya Bhaduri (now Bachchan) has quite a short filmography, several of her films included husband Amitabh Bachchan. These include classics like Zanjeer, Abhimaan, Chupke Chupke and the mother of all Bollywood films, Sholay. However, they made the most waves in Silsila, which surprisingly didn’t do extremely well at the box office but went on to become a classic. That happened to be Jaya’s last film as a lead actress. The iconic couple later starred together as husband and wife in Kabhi Kushi Kabhie Gham where they proved that even after several years, the chemistry is still alive and kicking!