3. Abhishek Bachchan and Aishwarya Rai Bachchan
This couple ranked number 4 on our 2006 list and, though better last year, their filmi jodi was considered only so-so. The two started dating in real life and everyone was watching to see how that would translate on screen. We got the answer in the film Guru, where we, for first time, saw real chemistry between them. The love between the two characters seemed true and the pairing in the film worked wonderfully, factors that made Guru one of the biggest hits of 2007! Their chemistry offscreen as well was love, and they married in April of this year.